Extra electronic outer-shell peculiarities accessible under a joint XPS and DFT study.

Electronic configuration of chemically bound atoms at the surface, including adsorbed species, or in the bulk of a solid contains a set of natural traps for energy absorption provided by valence band transitions or plasmon oscillations. The core level excitation of any origin is generally coupled with those traps, forming a multichannel route for nonradiative energy dissipation. Using an example of Pt and graphite-based materials, the study shows experimental tracing over these channels by means of elastic electron scattering and X-ray photoelectron spectroscopy. As a complement to the experimental data, calculations of the density of states provide information on chemical behavior and local geometry of the atoms in a sample.